Speed of sound data and acoustic virial coefficients of two binary (N2 + H2) mixtures at temperatures between (260 and 350) K and at pressures between (0.5 and 20) MPa

نویسندگان

چکیده

• New experimental speed of sound data and acoustic virial coefficients (N 2 + H ) mixtures. The performance three established reference thermodynamic models is assessed. Beckmüller et al. EoS (10.1063/5.0040533) performs best within the studied ranges. This work aims to address technical concerns related characterization gas mixtures blended with hydrogen for implementation as a new energy vector. For this purpose, measurements have been done in gaseous supercritical phases two binary nitrogen using most accurate technique available, i.e., spherical resonator, yielding an expanded ( k = 2) uncertainty only 220 parts 10 6 (0.022%). cover pressure range between (0.5 20) MPa, temperature (260 350) K, composition nominal mole percentage (5 10) mol%, respectively. From sets, thermophysical properties that are relevant mixture, namely second β third γ coefficients, derived. These results thoroughly compared discussed mixture valid hydrogen, such AGA8-DC92 EoS, GERG-2008 recently developed adaptation here denoted GERG- _improved EoS. Special attention has given effect concentration on those properties, showing consistent sets measuring conditions.

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ژورنال

عنوان ژورنال: The Journal of Chemical Thermodynamics

سال: 2022

ISSN: ['1096-3626', '0021-9614']

DOI: https://doi.org/10.1016/j.jct.2022.106791